TiO2 is a common compound in paints due to the characteristics it induces in different paint products.
This guide uncovers facts on the importance of TiO2 in paints, its applications, key perks, considerations while choosing, and optimization essentials. Lets dig in deeper!
Paint with Titanium Dioxide
Several reasons exist which make TiO2 an essential ingredient in paints. The key reasons are:
Addition of TiO2 results in a plethora of benefits, especially in paint products.
Find highlight on key perks right below:
TiO2 in Paint
The infrared light-reflecting property of TiO2 can help save energy. It keeps the interior of your house cooler by providing better insulation. Thus it reduces the need for air-conditioners. TiO2 is non-toxic, which means it contains no harmful elements that pollute the environment. Besides that, it can act as a photocatalyst to decompose environmental pollutants.
TiO2 plays its part in increasing the overall opacity of paints. It reduces the need for painting multiple coats, reducing the total cost and avoiding waste.
TiO2 adds up hardness to the molecules of the paint. It is resistant to weathering and prevents paint degradation, thus making it last longer.
TiO2 reflects infrared light to retain gloss and appear shiny. This property enhances the painted surface aesthetic and insulates the surface against heat. Thus making a particular vicinity more appealing and engaging.
TiO2 is stable against UV rays and prevents the degradation of paint. A greater refractive index is solely responsible for the better light bending phenomenon.
In other words, if UV light pertains for longer, it results in fading of the color with time. But TiO2 in paints prevents this from happening.
Titanium Dioxide Grades
Rutile-type TiO2 offers a higher level of bending or scattering. The rutile type has wide adoptability than the anatase type because of its greater refractive index value. This thing makes rutile type TiO2 desirable in paint products.
There is not a single rutile TiO2 grade that suits best when it comes to paints or coatings. This is why industries use two or more pigments to enhance multiple properties of color.
Some of the key styles, along with their uses and characteristics ranges, are right in the table below for your reference:
Sr. No. Type 1 Type 2 Type 3 Type 4 Type 5 Type 6 Type 7 ASTM Standards 1 Anatase No chalk resistance RutileLow medium chalk resistance
Rutile medium chalk resistance Rutile higher chalk resistance Rutile high resistance to chalk Rutile medium-high resistance to chalk Rutile medium-high resistance to chalk D 2 Usage Coating for interior and exterior Low medium percentage PVC Percentage of PVC is high Highly durable exterior surface coatings Best for outer surface and high durability Interior exterior coatings medium high rate PVC Interior exterior coatings low high percentage PVC 3 TiO2 content (%) 93 9` 79 79 89 89 91 D 4 Specific resistivity, (minimum), Ω D 5 Moisture content in packed form, minimum, (%) 0.6 0.6 1.4 1.4 1.0 0.6 0.6 D 279 6 Specific gravity 3.7 4.0 4.1 4.3 3.7 4.2 3.7 4.2 3.7 4.2 3.7 4.2 4.1 4.3 D 152 7 45-µm screen residue, max, (%) 0.1 0.1 0.1 0.1 0.1 0.1 0.1 D 184 8 (TiO2) content, min, (%) 93 91 79 79 89 89 91 D 9 Specific resistance, min, Ω DThe efficiency of each particle matters in paints. To get the most out of paint products, it is essential to optimize TiO2. Find insights on the process of doing it effectively:
The term dispersion means separating the TiO2 particle in a way where there is some distance in between. The main reason is that when the particles are separated, they scatter light most effectively.
In natural existence form, the TiO2 particles have a strong bonding force between them. This requires sufficient work to isolate the particles from each other.
TiO2 Paint
There are two main types of equipment that you can use to break the bonding forces between the TiO2 particles:
As the name reflects, the disk dispenser comprises a disk with edges or blades with upward and downward projections. They receive rotational power from a shaft connected to the motor. For optimization, you must place the solution containing the dispersant and TiO2 under the disk dispenser.
As you are familiar with, the TiO2 particles feature better bonding. This leads to flocculation. The term flocculation means grouping particles to form a cluster. To disperse them effectively, you need to use a dispersant.
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The main function of the dispersant is to adsorb on the pigment surface and eliminate the flocculation or bonding phenomenon. A dispersant consists of several anchor groups that utilize long chains for better stabilization. In general, they have higher molecular weight. The anchor part settles on the surface of the pigment and chains projecting directly from the anchors.
In electrostatic optimization, the electromagnetic forces induce the charges on the pigment particles. Negative charge underneath and a positive on the outer surface. This way, it eliminates the flocculation and results in better optimization. It is perfect for higher polarity systems.
Electrostatic Optimization
In steric optimization, the anchors and their chains are a barrier between the different pigment particles. These chains and anchors play a part in eliminating clusters or lumps.
Steric Optimization
The benefits of dispersion include
It would help if you maximized the distance between the particles to achieve better scattering or bending efficiency. Here the filler materials serve you the best. Although they dont add up to the bending or scattering efficiency, they can be useful for maintaining the distance between the pigment particles.
You can experience crowding in this situation. Also, when the particle size is identical to the TiO2 particles, the distance between them refers to even spacing.
Particle Distribution
Choosing the right paint pigment requires you to pay attention to multiple aspects.
You can quickly check these three selection criteria in the technical documentation from the pigment producer.
Try to select the pigment with the right crystal structure, having the desired light scattering power. When it comes to light bending or preventing their penetration into an object rutile type performs better. A greater refractive index makes this happen.
Accurate or correct particle sizing in paint leads you to experience better performance and results. This will help you achieve better scattering.
Scattering Efficiency of TiO2 particles
The application to which you will subject the end product determines the composition/amount that a final inorganic treatment takes. This, in the end, have a great impact on the overall photoactivity. When employing TiO2 paint for exterior coatings, choose silica, alumina, and zirconia. This is true, especially for rutile grade TiO2.
The applicability of the paints having TiO2 is vast. Get insights on key notable applications:
Ti-Pure R-706 is the widely recommended TiO2 grade for paint due to its exceptional properties. Its high gloss and outstanding exterior durability makes it stand out. Put it either on the exteriors or interiors as per your requirement.
There is no perfect substitute for titanium dioxide in paints. However, several products like talc and carbonate can improve the coatings performance. Partial alternatives to TiO2 can reduce overall formulation costs while maintaining a high-quality product. Paint manufacturers can use functional extenders to modify the refractive index and optimize spacing.
Due to its versatile nature, you will find titanium dioxide in almost all paints. Its superior light-reflecting property and other characteristics make it suitable for the paint industry, including spray paints.
Ultra premium flat white paint has the highest amount of TiO2. It reflects light much better than semi-gloss paints with low content of TiO2.
Yes, powdered TiO2 in paint is safe due to its non-volatile nature. Solid TiO2 particles get firmly embedded into a polymer layer on the painted surface, minimizing the danger of loosening particles from the dried film. Therefore, there is no risk of inhaling or ingesting the powder particles.
With the increasing environmental and energy crisis, TiO2 is the future of the paint industry. Its white color, and remarkable properties make it an ideal choice for painting surfaces.
For you TiO2 for paint, contact Inter-China Chemical.